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Mechanical Property Characterization of a Polymeric Nanocomposite Reinforced by Graphitic Nanofibers with Reactive Linkers

L. Roy Xu

Department of Civil and Environmental Engineering, Vanderbilt Institute of Nanoscale Science and Engineering, Vanderbilt University, Nashville, TN 37235, USAl.roy.xu{at}vanderbilt.edu

Vikram Bhamidipati

Department of Civil and Environmental Engineering, Vanderbilt Institute of Nanoscale Science and Engineering, Vanderbilt University, Nashville, TN 37235, USA

Wei-Hong Zhong

Jiang Li

Charles M. Lukehart

Department of Chemistry, Vanderbilt Institute of Nanoscale Science and Engineering, Vanderbilt University, Nashville, TN 37235, USA

Edgar Lara-Curzio

Kenneth C. Liu

Michael J. Lance

Metals and Ceramics Division, Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, TN 37831, USA

Mechanical property characterization including bending, tensile, and fracture properties for a new functionalized nanofiber/epoxy composite were conducted. Results show that there was only very little increase in mechanical properties of nanocomposites although we used GCNF-ODA reactive linkers to improve the interface. The interfacial stress level of nanocomposites should be much higher than that of traditional composites because of high property mismatch between the nanoscale reinforcement and the matrix. In order to design strong and stiff nanocomposite materials, one should use aligned nanofibers with a relatively large volume or weight fraction. Also, the length of the nanofiber should be long enough and its diameter not very small in order to facilitate the interfacial load transfer mechanism.

Key Words: nanocomposite materials • graphite nanofibers • epoxy matrix • ultrasonic processing • mechanical property characterization

Journal of Composite Materials, Vol. 38, No. 18, 1563-1582 (2004)
DOI: 10.1177/0021998304043758


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